國內外有不少科研機構和專業廠商都在研究如何能在線地測定這些水質替換參數。
目前,在線自動分析儀的主要技術原理有化學滴定法、電化學丈量法、可見和紫外分光光度法[7]。第1種方法的原理是通過化學滴定來確定水質參數的含量。其缺點是丈量時間過長、操縱維護複雜,運行本錢高,同時還會產生二次汙染。第2種(zhong)方(fang)法(fa)的(de)原(yuan)理(li)是(shi)利(li)用(yong)水(shui)中(zhong)有(you)機(ji)物(wu)在(zai)工(gong)作(zuo)電(dian)極(ji)表(biao)麵(mian)被(bei)氧(yang)化(hua)的(de)同(tong)時(shi),工(gong)作(zuo)電(dian)極(ji)上(shang)將(jiang)有(you)電(dian)流(liu)變(bian)化(hua),當(dang)工(gong)作(zuo)電(dian)極(ji)的(de)電(dian)位(wei)衡(heng)定(ding)時(shi),電(dian)流(liu)的(de)變(bian)化(hua)與(yu)水(shui)中(zhong)的(de)水(shui)質(zhi)參(can)數(shu)成(cheng)線(xian)性(xing)關(guan)係(xi)。通(tong)過(guo)計(ji)算(suan)電(dian)流(liu)的(de)變(bian)化(hua)便(bian)可(ke)測(ce)出(chu)水(shui)質(zhi)參(can)數(shu)。其(qi)主(zhu)要(yao)特(te)點(dian)是(shi)丈(zhang)量(liang)速(su)度(du)快(kuai),儀(yi)器(qi)結(jie)構(gou)簡(jian)單(dan),沒(mei)有(you)二(er)次(ci)汙(wu)染(ran)。缺(que)點(dian)是(shi)通(tong)過(guo)不(bu)同(tong)電(dian)化(hua)學(xue)法(fa)產(chan)生(sheng)的(de)電(dian)極(ji)電(dian)流(liu)變(bian)化(hua)隻(zhi)和(he)一(yi)種(zhong)替(ti)換(huan)參(can)數(shu)有(you)線(xian)性(xing)關(guan)係(xi),和(he)其(qi)他(ta)水(shui)質(zhi)參(can)數(shu)則(ze)存(cun)在(zai)非(fei)線(xian)性(xing)的(de)關(guan)係(xi)。因(yin)此(ci)一(yi)般(ban)以(yi)電(dian)化(hua)學(xue)法(fa)為(wei)原(yuan)理(li)的(de)在(zai)線(xian)分(fen)析(xi)儀(yi)隻(zhi)能(neng)丈(zhang)量(liang)一(yi)種(zhong)水(shui)質(zhi)參(can)數(shu)[2]。第3種zhong方fang法fa是shi建jian立li在zai吸xi收shou定ding律lv之zhi上shang的de一yi種zhong利li用yong被bei測ce物wu質zhi的de分fen子zi或huo離li子zi對dui特te征zheng電dian磁ci輻fu射she的de吸xi收shou程cheng度du進jin行xing定ding量liang分fen析xi的de方fang法fa。實shi驗yan證zheng實shi,紫zi外wai吸xi光guang度du能neng反fan映ying水shui中zhong有you機ji汙wu染ran的de程cheng度du,特te別bie是shi對dui水shui中zhong的de一yi大da類lei芳fang香xiang族zu有you機ji物wu和he帶dai雙shuang鍵jian有you機ji物wu尤you為wei靈ling敏min。很hen多duo資zi料liao亦yi表biao明ming紫zi外wai吸xi光guang度du和he一yi些xie主zhu要yao水shui質zhi替ti換huan參can數shu具ju有you一yi定ding的de相xiang關guan性xing[4],因yin此ci,通tong過guo分fen析xi紫zi外wai吸xi光guang度du來lai獲huo得de水shui質zhi參can數shu具ju有you極ji為wei重zhong要yao的de理li論lun與yu實shi際ji意yi義yi。該gai文wen介jie紹shao的de是shi一yi種zhong新xin型xing在zai線xian紫zi外wai光guang譜pu水shui質zhi分fen析xi儀yi,以yi紫zi外wai分fen光guang光guang度du法fa為wei原yuan理li,采cai集ji水shui樣yang在zai紫zi外wai區qu的de全quan波bo段duan光guang譜pu,通tong過guo分fen析xi光guang譜pu數shu據ju的de相xiang關guan性xing,獲huo得de全quan光guang譜pu中zhong的de特te征zheng光guang譜pu。然ran後hou利li用yong智zhi能neng軟ruan件jian的de算suan法fa分fen析xi光guang譜pu和he各ge水shui質zhi參can數shu的de關guan係xi,建jian立li相xiang關guan猜cai測ce模mo型xing。實shi驗yan結jie果guo表biao明ming,該gai水shui質zhi分fen析xi儀yi有you丈zhang量liang速su度du快kuai、精度高、跟蹤性能好、操縱簡便的特點,和同類產品相比具有極大的上風。
目前,在線自動分析儀的主要技術原理有化學滴定法、電化學丈量法、可見和紫外分光光度法[7]。第1種方法的原理是通過化學滴定來確定水質參數的含量。其缺點是丈量時間過長、操縱維護複雜,運行本錢高,同時還會產生二次汙染。第2種(zhong)方(fang)法(fa)的(de)原(yuan)理(li)是(shi)利(li)用(yong)水(shui)中(zhong)有(you)機(ji)物(wu)在(zai)工(gong)作(zuo)電(dian)極(ji)表(biao)麵(mian)被(bei)氧(yang)化(hua)的(de)同(tong)時(shi),工(gong)作(zuo)電(dian)極(ji)上(shang)將(jiang)有(you)電(dian)流(liu)變(bian)化(hua),當(dang)工(gong)作(zuo)電(dian)極(ji)的(de)電(dian)位(wei)衡(heng)定(ding)時(shi),電(dian)流(liu)的(de)變(bian)化(hua)與(yu)水(shui)中(zhong)的(de)水(shui)質(zhi)參(can)數(shu)成(cheng)線(xian)性(xing)關(guan)係(xi)。通(tong)過(guo)計(ji)算(suan)電(dian)流(liu)的(de)變(bian)化(hua)便(bian)可(ke)測(ce)出(chu)水(shui)質(zhi)參(can)數(shu)。其(qi)主(zhu)要(yao)特(te)點(dian)是(shi)丈(zhang)量(liang)速(su)度(du)快(kuai),儀(yi)器(qi)結(jie)構(gou)簡(jian)單(dan),沒(mei)有(you)二(er)次(ci)汙(wu)染(ran)。缺(que)點(dian)是(shi)通(tong)過(guo)不(bu)同(tong)電(dian)化(hua)學(xue)法(fa)產(chan)生(sheng)的(de)電(dian)極(ji)電(dian)流(liu)變(bian)化(hua)隻(zhi)和(he)一(yi)種(zhong)替(ti)換(huan)參(can)數(shu)有(you)線(xian)性(xing)關(guan)係(xi),和(he)其(qi)他(ta)水(shui)質(zhi)參(can)數(shu)則(ze)存(cun)在(zai)非(fei)線(xian)性(xing)的(de)關(guan)係(xi)。因(yin)此(ci)一(yi)般(ban)以(yi)電(dian)化(hua)學(xue)法(fa)為(wei)原(yuan)理(li)的(de)在(zai)線(xian)分(fen)析(xi)儀(yi)隻(zhi)能(neng)丈(zhang)量(liang)一(yi)種(zhong)水(shui)質(zhi)參(can)數(shu)[2]。第3種zhong方fang法fa是shi建jian立li在zai吸xi收shou定ding律lv之zhi上shang的de一yi種zhong利li用yong被bei測ce物wu質zhi的de分fen子zi或huo離li子zi對dui特te征zheng電dian磁ci輻fu射she的de吸xi收shou程cheng度du進jin行xing定ding量liang分fen析xi的de方fang法fa。實shi驗yan證zheng實shi,紫zi外wai吸xi光guang度du能neng反fan映ying水shui中zhong有you機ji汙wu染ran的de程cheng度du,特te別bie是shi對dui水shui中zhong的de一yi大da類lei芳fang香xiang族zu有you機ji物wu和he帶dai雙shuang鍵jian有you機ji物wu尤you為wei靈ling敏min。很hen多duo資zi料liao亦yi表biao明ming紫zi外wai吸xi光guang度du和he一yi些xie主zhu要yao水shui質zhi替ti換huan參can數shu具ju有you一yi定ding的de相xiang關guan性xing[4],因yin此ci,通tong過guo分fen析xi紫zi外wai吸xi光guang度du來lai獲huo得de水shui質zhi參can數shu具ju有you極ji為wei重zhong要yao的de理li論lun與yu實shi際ji意yi義yi。該gai文wen介jie紹shao的de是shi一yi種zhong新xin型xing在zai線xian紫zi外wai光guang譜pu水shui質zhi分fen析xi儀yi,以yi紫zi外wai分fen光guang光guang度du法fa為wei原yuan理li,采cai集ji水shui樣yang在zai紫zi外wai區qu的de全quan波bo段duan光guang譜pu,通tong過guo分fen析xi光guang譜pu數shu據ju的de相xiang關guan性xing,獲huo得de全quan光guang譜pu中zhong的de特te征zheng光guang譜pu。然ran後hou利li用yong智zhi能neng軟ruan件jian的de算suan法fa分fen析xi光guang譜pu和he各ge水shui質zhi參can數shu的de關guan係xi,建jian立li相xiang關guan猜cai測ce模mo型xing。實shi驗yan結jie果guo表biao明ming,該gai水shui質zhi分fen析xi儀yi有you丈zhang量liang速su度du快kuai、精度高、跟蹤性能好、操縱簡便的特點,和同類產品相比具有極大的上風。
係統丈量原理
該gai儀yi器qi就jiu是shi一yi種zhong以yi紫zi外wai分fen光guang光guang度du法fa為wei原yuan理li的de水shui質zhi分fen析xi儀yi。和he國guo外wai同tong原yuan理li的de分fen析xi儀yi不bu同tong的de是shi,國guo外wai儀yi器qi采cai用yong的de光guang源yuan隻zhi產chan生sheng單dan一yi波bo長chang的de光guang譜pu,這zhe是shi由you於yu紫zi外waiUV254與CODjinsichengxianxingguanxi,erqitabochangheshuizhicanshudeguanxizebijiaofuza。weilebusangshiqitabochangsuotigongdeguanyushuizhicanshudeyouyongxinxi,gaiyiqishiyongdeguangyuanchansheng250~470nm的de光guang譜pu,通tong過guo智zhi能neng軟ruan件jian分fen析xi不bu同tong波bo長chang對dui水shui質zhi參can數shu變bian化hua的de影ying響xiang,建jian立li兩liang者zhe的de關guan係xi模mo型xing。而er且qie不bu少shao國guo外wai儀yi器qi在zai使shi用yong中zhong或huo多duo或huo少shao會hui用yong到dao一yi些xie化hua學xue試shi劑ji。如ru日ri本benDKK-TOA公司的幾款水質分析儀就是屬於這種類型。筆者設計的儀器在使用中則不需要任何化學試劑,因此能更迅速、直接地獲得各種水質參數。相比以往的各種水質分析儀,該係統具有丈量速度快、可重複性好、本錢低、不形成二次汙染的優點。
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